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Solvent Extraction Method of Edible Oil Using Hexane

Introduction

The solvent extraction method is one of the most widely used industrial processes for producing edible oils from oilseeds such as soybean, sunflower, groundnut, rice bran, cottonseed, mustard, and corn germ.
This method is especially preferred when the oil content of seeds is low or when maximum oil recovery is required.

Among various solvents, hexane is the most commonly used solvent in the edible oil industry due to its high oil solubility, low boiling point, easy recovery, and cost-effectiveness.


Why Hexane Is Used as a Solvent

Hexane is a petroleum-derived organic solvent that has ideal properties for oil extraction:

·  Excellent solubility for vegetable oils

·  Low boiling point (~65–70°C), making recovery easy

·  Chemically stable and non-reactive with oil

·  High extraction efficiency (up to 98–99%)

·  Economical and reusable after recovery

Because of these advantages, food-grade hexane is widely accepted in edible oil processing plants worldwide.


Raw Materials Used

Solvent extraction is mainly used for:

·  Soybean

·  Rice bran

·  Sunflower seed

·  Cottonseed

·  Mustard seed

·  Groundnut cake (after expelling)

·  Corn germ


Step-by-Step Solvent Extraction Process

1. Seed Preparation

Oilseeds are first cleaned to remove dust, stones, metal particles, and foreign matter.
Then they undergo:

·  Dehulling (removal of husk, if required)

·  Crushing or flaking to increase surface area

·  Conditioning by heating to optimize oil release

Proper preparation ensures efficient solvent penetration.


2. Extraction with Hexane

Prepared flakes or cake are fed into the extractor.

·  Hexane is sprayed or percolated through the material

·  Oil dissolves into hexane, forming a mixture called miscella (oil + hexane)

·  The remaining solid material becomes defatted meal

At this stage:

·  Oil recovery can reach 98–99%

·  Minimal oil remains in the meal


3. Miscella Distillation (Oil Recovery)

The miscella is heated in distillation units:

·  Hexane evaporates at low temperature

·  Oil is separated and collected

·  Evaporated hexane is condensed and reused

The recovered oil at this stage is called crude oil.


4. Desolventizing of Meal

The defatted meal still contains traces of hexane.

·  Meal is sent to a Desolventizer-Toaster (DT)

·  Steam and heat remove remaining hexane

·  Hexane vapors are recovered and reused

The final meal is:

·  Safe for animal feed or food applications

·  High in protein (especially soybean meal)


5. Solvent Recovery System

To ensure safety and economy:

·  All hexane vapors are condensed

·  Recovered hexane is recycled back into the system

·  Losses are kept extremely low

Modern plants achieve over 99.5% solvent recovery.


Post-Extraction Refining of Oil

The crude oil obtained by solvent extraction is not directly edible.
It undergoes refining steps such as:

1.     Degumming – Removal of phospholipids

2.     Neutralization – Removal of free fatty acids

3.     Bleaching – Removal of color pigments

4.     Deodorization – Removal of odor and taste

After refining, the oil becomes Refined, Bleached, and Deodorized (RBD) edible oil, suitable for human consumption.


Advantages of Solvent Extraction Method

·  Very high oil recovery (maximum yield)

·  Economical for large-scale production

·  Suitable for low-oil-content seeds

·  Produces high-protein defatted meal

·  Continuous and automated process


Safety and Environmental Considerations

Hexane is flammable, so modern plants include:

·  Explosion-proof equipment

·  Vapor-tight systems

·  Fire detection and suppression

·  Strict monitoring of solvent losses

Food-grade hexane residues in oil are removed completely during refining, making the final oil safe for consumption as per international standards.


Conclusion

The solvent extraction method using hexane is a highly efficient, proven, and globally accepted technology for edible oil production.
It ensures maximum oil recovery, consistent quality, and economic viability, especially for large-scale edible oil plants.

With advanced solvent recovery and refining systems, this method plays a crucial role in meeting the growing global demand for high-quality edible oils.

 

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